Zhang, Lumin published the artcileCarbene reactivity from alkyl and aryl aldehydes, Product Details of C9H10O2, the main research area is aldehyde carbene reactivity chemoselective diastereoselective dimerization coupling heterocyclization deoxygenation; insertion ring expansion rearrangement.
Common aldehydes were readily converted (via stable α-acyloxy halide intermediates) to electronically diverse (donor or neutral) carbenes to facilitate >10 reaction classes was reported. This strategy enabled safe reactivity of nonstabilized carbenes from alkyl, aryl and formyl aldehydes via zinc carbenoids. Earth-abundant metal salts [iron(II) chloride, cobalt(II) chloride, copper(I) chloride] were effective catalysts for these chemoselective carbene additions to σ and π bonds.
Science (Washington, DC, United States) published new progress about Aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Product Details of C9H10O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics