Yuan, Zhenbo published the artcilePalladium-Catalyzed Asymmetric Intramolecular Reductive Heck Desymmetrization of Cyclopentenes: Access to Chiral Bicyclo[3.2.1]octanes, Application of Benzyl acetate, the main research area is cyclopentenyl haloarylmethanone preparation palladium catalyst intramol reductive Heck desymmetrization; tetrahydromethanobenzoannulene carboxylate enantioselective preparation; Heck reaction; asymmetric catalysis; bicyclic compounds; desymmetrization; palladium.
A palladium-catalyzed asym. reductive Heck reaction of unactivated aliphatic alkenes, with eliminable β-hydrogen atoms, was realized for the first time. A series of optically active bicyclo[3.2.1]octanes bearing chiral quaternary and tertiary carbon stereocenters were obtained in good yields with excellent enantioselectivities, exhibited good functional-group tolerance and scalability. Moreover, deuterated optically active bicyclo[3.2.1]octanes were also obtained in high efficiency.
Angewandte Chemie, International Edition published new progress about Aromatic esters Role: RCT (Reactant), RACT (Reactant or Reagent). 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Application of Benzyl acetate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics