Sousa, Sara C. A. published the artcileBench-Stable Manganese NHC Complexes for the Selective Reduction of Esters to Alcohols with Silanes, HPLC of Formula: 111-11-5, the main research area is alc preparation chemoselective; ester reduction manganese catalyst.
Selective reduction of esters to alcs. RCH2OH [R = cyclohexyl, Ph, 4-ClC6H4, etc.] was accomplished through Mn(I)-mediated hydrosilylation reaction. The manganese tricarbonyl complex [Mn(bis-NHC)(CO)3Br] resulted an active pre-catalyst for the reduction of a variety of esters using phenylsilane and the cheap and readily available polymethylhydrosiloxane.
Advanced Synthesis & Catalysis published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, HPLC of Formula: 111-11-5.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics