Satake, Akiharu’s team published research in Chemistry Letters in 1999-01-31 | CAS: 86549-27-1

Chemistry Letters published new progress about Acetals, ketene Role: RCT (Reactant), RACT (Reactant or Reagent) (silyl). 86549-27-1 belongs to class esters-buliding-blocks, name is Ethyl 2,2-dimethylpent-4-enoate, and the molecular formula is C9H16O2, COA of Formula: C9H16O2.

Satake, Akiharu published the artcileCyclopropanation of ketene silyl acetals with allylic acetates using η3-allylpalladium-pyridinylimidazole catalysts, COA of Formula: C9H16O2, the main research area is cyclopropanation ketene silyl acetal allyl acetate; stereoselective cyclopropanation cyclopropanation ketene silyl acetal allyl acetate; stereochem cyclopropanation ketene silyl acetal allyl acetate; phenyl cyclopropane preparation.

Highly selective cyclopropanation of ketene silyl acetals with allylic acetates was carried out in the presence of novel η3-allylpalladium-pyridinylimidazole complexes and sodium acetate in DMSO at room temperature When cinnamyl acetate was used as an allylic acetate, phenylcyclopropane derivative was obtained stereoselectively in 83% yield.

Chemistry Letters published new progress about Acetals, ketene Role: RCT (Reactant), RACT (Reactant or Reagent) (silyl). 86549-27-1 belongs to class esters-buliding-blocks, name is Ethyl 2,2-dimethylpent-4-enoate, and the molecular formula is C9H16O2, COA of Formula: C9H16O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics