Olivier, Wesley J. published the artcileBronsted acid-mediated annulations of pyrroles featuring N-tethered α,β-unsaturated ketones and esters: Total syntheses of (±)-tashiromine and (±)-indolizidine 209I, Quality Control of 10047-10-6, the main research area is tashiromine total synthesis pyrrole Bronsted acid mediated annulation; indolizidine 209I total synthesis pyrrole Bronsted acid mediated annulation.
This study provides the first report of the construction of tetrahydroindolizines and tetrahydropyrrolo[1,2-a]azepines via Bronsted acid-mediated annulation of pyrroles featuring N-tethered α,β-unsaturated esters. In addition, the Bronsted acid-catalyzed cyclization of pyrroles featuring pendant α,β-unsaturated ketones was applied to complete total syntheses of the indolizidine alkaloids (±)-tashiromine (I) and (±)-indolizidine 209I (II).
Tetrahedron published new progress about Bronsted acids Role: RGT (Reagent), RACT (Reactant or Reagent). 10047-10-6 belongs to class esters-buliding-blocks, name is Methyl 2-aminopentanoate hydrochloride, and the molecular formula is C6H14ClNO2, Quality Control of 10047-10-6.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics