Nakajima, Takumi’s team published research in Chemistry – An Asian Journal in 2021-12-13 | CAS: 583-04-0

Chemistry – An Asian Journal published new progress about Disulfides Role: RCT (Reactant), RACT (Reactant or Reagent). 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, COA of Formula: C10H10O2.

Nakajima, Takumi published the artcileProduction of Alkyl Aryl Sulfides from Aromatic Disulfides and Alkyl Carboxylates via a Disilathiane-Disulfide Interchange Reaction, COA of Formula: C10H10O2, the main research area is alkyl aryl sulfide preparation; aromatic disulfide alkyl carboxylate interchange; alkyl carboxylate; carbon-sulfur bond formation; disilathiane; disulfide; sulfur-sulfur bond cleavage.

The results of this study show that disilathiane was an effective mediator in the synthesis of alkyl aryl sulfides RSR1 [R = Me, Et, Bn, etc.; R1 = Ph, 4-MeC6H4, 2-naphthyl, etc.] with disulfides and alkyl carboxylates. Mechanistic studies suggested that disilathiane promotes cleavage of the sulfur-sulfur bond of disulfides to generate thiosilane as a key intermediate. Diselenides were also applicable to this transformation to produce the corresponding selenides.

Chemistry – An Asian Journal published new progress about Disulfides Role: RCT (Reactant), RACT (Reactant or Reagent). 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, COA of Formula: C10H10O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics