Lv, Wen-Rui published the artcileSynthesis, Structure, and Catalytic Hydrogenation Activity of [NO]-Chelate Half-Sandwich Iridium Complexes with Schiff Base Ligands, Safety of Ethyl 3-hydroxybutanoate, the main research area is enaminoketonate sandwich iridium Schiff base complex preparation hydrogenation catalyst; iridium Schiff base complex catalyst hydrogenation ketone aldehyde nitro; crystal structure half sandwich iridium enaminoketonate Schiff base complex; mol structure half sandwich iridium enaminoketonate Schiff base complex.
N,O-coordinate Ir(III) complexes with a half-sandwich motif bearing Schiff base ligands for catalytic hydrogenation of nitro and carbonyl substrates were synthesized. All Ir complexes showed efficient catalytic activity for the hydrogenation of ketones, aldehydes, and nitro-containing compounds using clean H2 as reducing reagent. The Ir catalyst displayed the highest TON values of 960 and 950 in the hydrogenation of carbonyl and nitro substrates, resp. Various types of substrates with different substituted groups afforded corresponding products in excellent yields. All N,O-coordinate Ir(III) complexes 1-4 were well characterized by IR, NMR, HRMS, and elemental anal. The mol. structure of complex 1 was further characterized by single-crystal x-ray determination
Inorganic Chemistry published new progress about Aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 5405-41-4 belongs to class esters-buliding-blocks, name is Ethyl 3-hydroxybutanoate, and the molecular formula is C6H12O3, Safety of Ethyl 3-hydroxybutanoate.
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