Kar, Sayan published the artcileDehydrogenative ester synthesis from enol ethers and water with a ruthenium complex catalyzing two reactions in synergy, Related Products of esters-buliding-blocks, the main research area is ruthenium complex catalyst preparation ester synthesis; ester chemoselective dehydrogenative preparation mechanism; vinyl enol ether oxidation ruthenium complex catalyst mechanism; cyclic enol ether oxidation ruthenium complex catalyst mechanism.
The authors report the dehydrogenative synthesis of esters RO2CMe [R = Et, n-Bu, Bn, etc.] from enol ethers using water as the formal oxidant, catalyzed by a newly developed ruthenium acridine-based PNP(Ph)-type complex. Mechanistic experiments and d. functional theory (DFT) studies suggest that an inner-sphere stepwise coupled reaction pathway was operational instead of a more intuitive outer-sphere tandem hydration-dehydrogenation pathway.
Green Chemistry published new progress about Carboxylic esters Role: SPN (Synthetic Preparation), PREP (Preparation). 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Related Products of esters-buliding-blocks.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics