Hendrickson, James B. published the artcileNuclear synthons: mesyltriflone as an olefin polyanion equivalent, Application In Synthesis of 39495-82-4, the main research area is synthon mesyltriflone; regiochem mesyltriflone alkylation; Ramberg Baecklund mesyltriflone elimination; stereochem mesyltriflone elimination.
The title compound, CF3SO2CH2SO2Me, is a nuclear synthon capable first of multiple constructions (e.g., alkylations), and then of Ramberg-Baecklund elimination (to give substituted alkenes). The alkylations are clean and regiospecific, often amenable to one-pot operation, and in most cases the elimination is smooth. A variety of examples establish the scope of the method; the mechanism and stereochem. are discussed.
Journal of the American Chemical Society published new progress about Alkenes Role: SPN (Synthetic Preparation), PREP (Preparation). 39495-82-4 belongs to class esters-buliding-blocks, name is Ethyl 5-methylhex-5-enoate, and the molecular formula is C9H16O2, Application In Synthesis of 39495-82-4.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics