Gao, Yadong published the artcileVisible-Light-Induced Nickel-Catalyzed Cross-Coupling with Alkylzirconocenes from Unactivated Alkenes, Computed Properties of 110-42-9, the main research area is alkene alkyl iodide zirconocene nickel photochem regioselective cross coupling; aralkyl chloride alkene zirconocene nickel photochem regioselective cross coupling; aryl iodide alkene zirconocene nickel photochem regioselective cross coupling; unsaturated bromide alkene zirconocene nickel photochem regioselective cross coupling.
Visible-light-induced single nickel-catalyzed C(sp3)-C(sp3), C(sp3)-C(sp2) and C(sp3)-C(sp) cross-coupling reactions were reported using alkylzirconocenes, which were easily generated in-situ from terminal or internal unactivated alkenes through hydrozirconation and chain walking. This method was mild and applicable for a large range of substrates including primary, secondary, tertiary alkyl, aryl, alkenyl, alkynyl halides and a variety of alkenes. Mechanistic studies suggested a novel nickel-catalyzed radical cross-coupling pathway, which represented the first visible-light-induced transformation of alkylzirconocenes.
Chem published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 110-42-9 belongs to class esters-buliding-blocks, name is Methyl decanoate, and the molecular formula is C11H22O2, Computed Properties of 110-42-9.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics