Das, Uttam Kumar published the artcileDehydrogenative Cross-Coupling of Primary Alcohols To Form Cross-Esters Catalyzed by a Manganese Pincer Complex, SDS of cas: 111-11-5, the main research area is primary alc manganese pincer complex catalyst dehydrogenative cross coupling; cross ester preparation.
Base-metal-catalyzed dehydrogenative cross-coupling of primary alcs. to form cross-esters as major products, liberating hydrogen gas, is reported. The reaction is catalyzed by a pincer complex of earth-abundant manganese in the presence of catalytic base, without any hydrogen acceptor or oxidant. Mechanistic insight indicates that a dearomatized complex is the actual catalyst, and indeed this independently prepared dearomatized complex catalyzes the reaction under neutral conditions.
ACS Catalysis published new progress about Carboxylic esters Role: SPN (Synthetic Preparation), PREP (Preparation). 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, SDS of cas: 111-11-5.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics