Chen, Yaoyao published the artcileBu4NI-Catalyzed C-C Bond Cleavage and Oxidative Esterification of Allyl Alcohols with Toluene Derivatives, Formula: C9H10O2, the main research area is arylpropenol toluene oxidative esterification tetrabutylammonium iodide catalyst; ester preparation.
A novel oxidative esterification of 1-arylprop-2-en-1-ols R1CH(OH)CH=CHR2 (R1 = Ph, 2-chlorophenyl, 4-bromophenyl, etc.; R2 = H, Me, 3-methoxyphenyl) with toluene derivatives ArMe (Ar = Ph, 3-chlorphenyl, 2-naphthyl, etc.) catalyzed by tetrabutylammonium iodide (TBAI) is reported. The optimization of the reaction conditions illustrates that each of experiment parameters including the catalyst, solvent, and oxidant is significant for present oxidative functionalization. This metal-free protocol has a broad substrate scope including the halogen groups for further functionalization and enriches the reactivity profile of allyl alc. and toluene derivatives In addition, this protocol represents a new transformation of allyl alc. involving C-C bond cleavage and C-O bond forming.
Synthesis published new progress about Allylic alcohols Role: RCT (Reactant), RACT (Reactant or Reagent) (aryl). 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Formula: C9H10O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics