Selmani, Aymane published the artcileModularity in the Csp3 Space-Alkyl Germanes as Orthogonal Molecular Handles for Chemoselective Diversification, Related Products of esters-buliding-blocks, the publication is ACS Catalysis (2022), 12(9), 4833-4839, database is CAplus.
To meet the need for a rapid, streamlined, and potentially automatable mol. synthesis, modular coupling approaches are highly desired. While the diversification of aromatic mols., i.e., Csp2 space, has greatly advanced, modular syntheses in the Csp3 space are comparably much less developed. This report explores the potential of alternative functional handles, i.e., alkyl germanes, in this context, which combine features of stability and synthesizability with selective reactivity. The authors show the chemoselective functionalization of alkyl germanes (R-GeEt3) under photoredox conditions (Giese addition) and the implementation in a modular building block, which allows for selective diversification of Csp3-halogen vs. Csp3-Bpin vs. Csp3-GeEt3 sites.
ACS Catalysis published new progress about 624-49-7. 624-49-7 belongs to esters-buliding-blocks, auxiliary class Inhibitor,Natural product, name is Dimethyl fumarate, and the molecular formula is C7H8BFO2, Related Products of esters-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics