Kuwabe, Shin-itsu published the artcilePalladium-Catalyzed Intramolecular C-O Bond Formation, HPLC of Formula: 115314-17-5, the publication is Journal of the American Chemical Society (2001), 123(49), 12202-12206, database is CAplus and MEDLINE.
A number of oxygen heterocycles were synthesized using the palladium-catalyzed intramol. etherification of aryl halides by employing di-tert-butylphosphinobiaryl ligands. The reaction proceeds under mild conditions using weak bases such as Cs2CO3 or K3PO4. A variety of functional groups are tolerated in the reaction, and enantioenriched alcs. can be coupled without erosion of optical purity. The mildness of the reaction conditions allows for the use of polyfunctionalized substrates. This method was used as the key step in the synthesis of MKC-242, an antidepressant currently in clin. trials. The synthesis of MKC-242 was achieved in 40% overall yield from com. available sesamol and acrylonitrile.
Journal of the American Chemical Society published new progress about 115314-17-5. 115314-17-5 belongs to esters-buliding-blocks, auxiliary class Epoxides,Chiral,Nitro Compound,Sulfonate,Benzene, name is (R)-Oxiran-2-ylmethyl 3-nitrobenzenesulfonate, and the molecular formula is C9H9NO6S, HPLC of Formula: 115314-17-5.
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https://en.wikipedia.org/wiki/Ester,
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