Kantlehner, Willi’s team published research in Liebigs Annalen der Chemie in | CAS: 924-99-2

Liebigs Annalen der Chemie published new progress about 924-99-2. 924-99-2 belongs to esters-buliding-blocks, auxiliary class Alkenyl,Amine,Aliphatic hydrocarbon chain,Ester, name is Ethyl 3-(dimethylamino)acrylate, and the molecular formula is C7H13NO2, Computed Properties of 924-99-2.

Kantlehner, Willi published the artcileOrthoamides. XXXII. Reaction of tert-butoxy-N,N,N’,N’-tetramethylmethanediamine with NH- and CH-acidic compounds, Computed Properties of 924-99-2, the publication is Liebigs Annalen der Chemie (1980), 344-57, database is CAplus.

Me3COCH(NMe2)2 (I) reacted with OHCNHCH2(CH2)nCO2Et to give OHCNH(CH2)nC(CO2Et):CHNMe2, whereas H2NCH2CO2Et reacted with I to give Me2NCH:NCH2CO2Et, which reacted with I to give Me2NCH:NC(CO2Et):CHNMe2. HCONHR (R = Me, Et, Ph, Pr, PhCH2) were transformed by I into Me2NCH:NR. Reaction of EtO2CCH2NC with I gave EtO2CC(NC):CHNMe2, whereas reaction of PhCH2NC with I gave Me2NCH:CPhN:CHNMe2. The oxazolines II (R = H, Me), R1N:C(OEt)CH2R2 (R1, R2 = Me, Ph; Ph, H), and Me2NCMe:NR3 (R3 = Me, Ph) were aminomethylated by I to give III, Me2NCH:CR2C(OEt):NR1, and R3N:C(NMe2)CH:CHNMe2, resp. MeC+(NMe2)2BF4– reacted with I to give Me2NCH:CHC+(NMe2)2BF4–, whereas R4CH2P(O)(OEt)2 (R4 = Ph, CO2Et, cyano) reacted with I to give Me2NCH:CR4P(O)(OEt)2. Reaction of I with Me3SiCH2CO2Et yielded Me2NCH:CHCO2Et.

Liebigs Annalen der Chemie published new progress about 924-99-2. 924-99-2 belongs to esters-buliding-blocks, auxiliary class Alkenyl,Amine,Aliphatic hydrocarbon chain,Ester, name is Ethyl 3-(dimethylamino)acrylate, and the molecular formula is C7H13NO2, Computed Properties of 924-99-2.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics