Gupta, Aniket published the artcileCooperativity between the Substrate and Ligand in Palladium-Catalyzed Allylic Alkylation Using 1-Aryl-1-propynes, SDS of cas: 30414-53-0, the publication is Journal of Organic Chemistry (2022), 87(15), 10366-10371, database is CAplus and MEDLINE.
A monoprotected amino acid Bz-Gly-OH assists in the allylic alkylation of a variety of ketones, β-keto esters, aldehydes, etc., during enamine-palladium catalysis to gave alkylated products such as R1C(O)CHR2CH2CH=CHAr [R1 = Me, Et, n-Pr; R2 = Et, C(O)OMe, C(O)OEt, C(O)OBn, etc.; R1R2 = (CH2)3, (CH2)4, (CH2)5, etc.]. D. functional theory calculations revealed that Bz-Gly-OH assisted in the formation of an enamine that attacks the π-allylpalladium complex via an outer sphere mechanism. The preliminary result pointed to an asym. allylic alkylation under a new mode of bifunctional catalysis.
Journal of Organic Chemistry published new progress about 30414-53-0. 30414-53-0 belongs to esters-buliding-blocks, auxiliary class Aliphatic hydrocarbon chain,Ketone,Ester, name is Methyl 3-oxovalerate, and the molecular formula is C6H10O3, SDS of cas: 30414-53-0.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics