Fu, Niankai published the artcileElectrocatalytic Radical Dichlorination of Alkenes with Nucleophilic Chlorine Sources, Related Products of esters-buliding-blocks, the publication is Journal of the American Chemical Society (2017), 139(43), 15548-15553, database is CAplus and MEDLINE.
We report a Mn-catalyzed electrochem. dichlorination of alkenes with MgCl2 as the chlorine source. This method provides operationally simple, sustainable, and efficient access to a variety of vicinally dichlorinated compounds In particular, alkenes with oxidatively labile functional groups, such as alcs., aldehydes, sulfides, and amines, were transformed into the desired vicinal dichlorides with high chemoselectivity. Mechanistic data are consistent with metal-mediated Cl atom transfer as the predominant pathway enabling dual C-Cl bond formation and contradict an alternative pathway involving electrochem. evolution of chlorine gas followed by Cl2-mediated electrophilic dichlorination.
Journal of the American Chemical Society published new progress about 5205-11-8. 5205-11-8 belongs to esters-buliding-blocks, auxiliary class Alkenyl,Benzene,Ester, name is 3-Methylbut-2-en-1-yl benzoate, and the molecular formula is C12H14O2, Related Products of esters-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics