Wang, Peng published the artcileCatalytic Azido-Hydrazination of Alkenes Enabled by Visible Light: Mechanistic Studies and Synthetic Applications, Quality Control of 5205-11-8, the publication is Advanced Synthesis & Catalysis (2019), 361(24), 5565-5575, database is CAplus.
A visible-light-enabled catalytic intermol. azido-hydrazination method for unactivated alkenes was developed via an orderly radical addition sequence. This transformation features metal-free and redox-neutral conditions and was applicable to a wide range of alkenes with com. available reagents. Mechanistic and kinetic studies reveal that the efficient generation of azide radical enabled by fluorenone under visible-light was critical to this methodol. The β-azido alkyl hydrazines prepared with this reaction can be conveniently derived to valuable synthetic building blocks, and one of the products has been successfully applied in the total synthesis of (±)-ibrutinib, which was used to treat B cell cancers.
Advanced Synthesis & Catalysis published new progress about 5205-11-8. 5205-11-8 belongs to esters-buliding-blocks, auxiliary class Alkenyl,Benzene,Ester, name is 3-Methylbut-2-en-1-yl benzoate, and the molecular formula is C12H16N2O2, Quality Control of 5205-11-8.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics