Sokolov, Alexey S. published the artcileGeneration of Cyclopentadiene for Diels-Alder Reactions by Visible-Light Irradiation of Iron Sandwich Complexes, Synthetic Route of 624-49-7, the publication is Helvetica Chimica Acta (2022), 105(4), e202100246, database is CAplus.
Cyclopentadienes readily undergo fast and selective Diels-Alder reactions which can be used for conjugation of biomols. and polymers. Herein authors present a new method for the photochem. generation of cyclopentadienes by the visible light irradiation of the iron complexes [(C5H4R)Fe(arene)]+. This reaction proceeds at room temperature, in water, and in the presence of potentially interfering amino acids. Free cyclopentadiene is trapped by dienophiles to give the corresponding Diels-Alder adducts in 72-95% yield.
Helvetica Chimica Acta published new progress about 624-49-7. 624-49-7 belongs to esters-buliding-blocks, auxiliary class Inhibitor,Natural product, name is Dimethyl fumarate, and the molecular formula is C22H12F6O6S2, Synthetic Route of 624-49-7.
Referemce:
https://en.wikipedia.org/wiki/Ester,
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