Nghiem, Quoc Dat published the artcileControlled/living radical polymerization of vinylcyclicsilazane by RAFT process and their block copolymers, Computed Properties of 3052-61-7, the publication is Journal of Polymer Science, Part A: Polymer Chemistry (2008), 46(13), 4594-4601, database is CAplus.
High mol. weight poly(vinyl)silazane were synthesized successfully by reversible addition fragmentation chain transfer (RAFT) polymerization in toluene at 120 °C, using dithiocarbamate derivatives and 2,2′-azobis-isobutyrylnitrile (AIBN) as the RAFT agents and thermal initiator, resp. The polymerization of a vinylcyclicsilazane oligomer with 82.5% conversion was readily controlled to increase the mol. weight from 1000 to 12,000 g/mol with a narrow polydispersity <1.5. The resulting polymer showed a high ceramic yield of 70 wt % at 1000 °C. Moreover, the approach was extended successfully to the synthesis of poly(vinyl)silazane-block-polystyrene as an inorganic-organic diblock copolymer.
Journal of Polymer Science, Part A: Polymer Chemistry published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Computed Properties of 3052-61-7.
Referemce:
https://en.wikipedia.org/wiki/Ester,
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