Barton, Donald L. published the artcilePreparation of positive inotropes using glycidyl derivatives: influence of metal ions and solvent on stereochemical outcome, Safety of (R)-Oxiran-2-ylmethyl 3-nitrobenzenesulfonate, the publication is Tetrahedron: Asymmetry (1992), 3(9), 1189-96, database is CAplus.
The choice of base and solvent has a dramatic effect on the attack of nitrogen nucleophiles on enantiomerically enriched glycidyl sulfonates I (R = 4-Me, 3-NO2). Under the proper conditions attack can be largely limited to displacement of the sulfonate moiety thus retaining the original stereochem. Conditions were also noted where the initial attack resulted from epoxide opening. Subsequent attack of the intermediate alkoxide on the sulfonate group then yielded a product of opposite stereochem. The methodol. was applied to the syntheses of both enantiomers of carsatrin (II).
Tetrahedron: Asymmetry published new progress about 115314-17-5. 115314-17-5 belongs to esters-buliding-blocks, auxiliary class Epoxides,Chiral,Nitro Compound,Sulfonate,Benzene, name is (R)-Oxiran-2-ylmethyl 3-nitrobenzenesulfonate, and the molecular formula is C9H9NO6S, Safety of (R)-Oxiran-2-ylmethyl 3-nitrobenzenesulfonate.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics