Auvil, Tyler J. published the artcileInternal lewis acid assisted benzoic acid catalysis, Name: Methyl 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-(trifluoromethyl)benzoate, the publication is Synthesis (2012), 44(14), 2173-2180, database is CAplus.
Internal Lewis acid assisted benzoic acid derivatives are introduced as new low-mol.-weight single-hydrogen-bond donor catalysts for the activation of nitroalkenes. Selected 2-borylbenzoic acid derivatives gave good yields of products in the addition of indoles to nitroalkenes. Control experiments suggest that both the internal Lewis acid coordination and the carboxylic acid functionalities are critical to the optimal performance of these catalysts.
Synthesis published new progress about 1146214-86-9. 1146214-86-9 belongs to esters-buliding-blocks, auxiliary class Boronic acid and ester, name is Methyl 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-(trifluoromethyl)benzoate, and the molecular formula is C15H18BF3O4, Name: Methyl 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-(trifluoromethyl)benzoate.
Referemce:
https://en.wikipedia.org/wiki/Ester,
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