Padwa, Albert published the artcileEfficient Construction of the Oxatricyclo[6.3.1.00,0]dodecane Core of Komaroviquinone Using a Cyclization/Cycloaddition Cascade of a Rhodium Carbenoid Intermediate, Formula: C9H16O2, the main research area is oxatricyclododecane core komaroviquinone preparation cyclization cycloaddition cascade rhodium carbenoid.
The rhodium(II)-catalyzed cyclization/cycloaddition cascade of a o-carbomethoxyaryl diazo dione is described as a potential route to the oxatricyclo[6.3.1.00,0]dodecane substructure I (R = H, Me) of the icetexane diterpene komaroviquinone. The initially formed carbonyl ylide dipole prefers to cyclize to an epoxide at 25 °C but can be induced to undergo cycloaddition across the tethered π-bond at higher temperatures
Organic Letters published new progress about Cyclization. 86549-27-1 belongs to class esters-buliding-blocks, name is Ethyl 2,2-dimethylpent-4-enoate, and the molecular formula is C9H16O2, Formula: C9H16O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics