Jaoued-Grayaa, Najeh published the artcileDesign of molecularly imprinted polymer materials relying on hydrophobic interactions, Formula: C16H30O2, the main research area is acrylic molecularly imprinted polymer crosslinking hydrophobic silica adsorption kinetics.
The design of molecularly imprinted polymers (MIPs) for the specific binding of hydrophobic mols. (mitotane) was investigated by considering monomers and crosslinking agents with variable hydrophobic character, Me methacrylate, Bu methacrylate and lauryl methacrylate as functional monomers, and ethylene glycol dimethacrylate and 1,6-hexanediol dimethacrylate as crosslinking agents. MIPs were bound to a porous silica support by means of a radical transfer reaction with grafted 3-mercaptopropyl groups. Equilibrium adsorption isotherms to molecularly imprinted and non-imprinted materials were modeled with the Volmer and Langmuir-Volmer isotherms, giving the thermodn. parameters of adsorption. The most hydrophobic monomer provided the highest selective adsorption although strong non-selective adsorption and the intrinsic softness of poly(lauryl methacrylate) is detrimental to selectivity. Adsorption was exothermic with a predominant enthalpic contribution. Adsorption kinetics were fast due to the high accessibility of mol. imprints on the surface of the thin MIP layer coating the porous silica support.
Colloids and Surfaces, A: Physicochemical and Engineering Aspects published new progress about Adsorption. 142-90-5 belongs to class esters-buliding-blocks, name is Dodecyl 2-methylacrylate, and the molecular formula is C16H30O2, Formula: C16H30O2.
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Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics