Tian, Bing published the artcilePalladium-catalysed enantioselective diacetoxylation of terminal alkenes, Formula: C10H10O2, the main research area is terminal alkene preparation enantioselective diacetoxylation.
Abstract: Optically pure 1,2-diols are one of the most privileged structural motifs. They are not only frequently found in natural products and drugs, but are also regarded as very useful synthons in organic synthesis. Asym. dioxygenation of alkenes could potentially provide a highly efficient and straightforward method for the synthesis of enantioenriched 1,2-diols. Although enantioselective dioxygenations on different alkenes have been studied widely, those on terminal alkenes remain elusive. Herein, a Pd(II)-catalyzed enantioselective diacetoxylation of terminal alkenes, including challenging substrates such as 1-propene and 1-butene is reported. Notably, ligand engineering of the simple pyridinyl oxazoline ligand is essential for substantially increasing the catalytic reactivity of Pd(OAc)2. The method exhibits an exquisite selectivity for terminal alkenes, allowing precise asym. diacetoxylation reactions from feedstock alkenes to complex mols. bearing multiple alkenic moieties, which provides rapid and efficient access to various synthetically useful chiral 1,2-diols. [graphic not available: see fulltext].
Nature Catalysis published new progress about Acetoxylation. 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Formula: C10H10O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics