Cheng, Ming published the artcilePalladium-Catalyzed Carbene Migratory Insertion/Carbonylation Cascade Reaction: Synthesis of 2-Indolones with a C3 All-Carbon Quaternary Center, Application In Synthesis of 583-04-0, the main research area is indolone preparation; amino aryl diazo ester allyl carboxylate carbon monoxide; tandem carbene migratory insertion carbonylation.
An attractive palladium-catalyzed three-component reaction of ortho-amino aryl diazo esters, allyl carboxylates, and carbon monoxide (CO) has been developed. This catalytic system rendered domino carbene migratory insertion and carbonylation. Remarkably, 2-indolones with a C3 all-carbon quaternary center can be selectively obtained in good to excellent yields via one-pot synthesis, in which two different C-C bonds and one C-N bond were formed in a straightforward manner.
Organic Letters published new progress about Carbonylation. 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Application In Synthesis of 583-04-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics