Howard, Micheal Seamus published the artcileEthanolic gasoline, a lignocellulosic advanced biofuel, Related Products of esters-buliding-blocks, the main research area is ethanolic gasoline lignocellulosic biofuel combustion.
In line with society’s growing need for a more sustainable fuel economy, various biofuels and alternative fuel formulations are being proposed. In this work, the ignition quality of a novel tricomponent advanced biofuel is examined Et levulinate, di-Et ether and ethanol (EL/DEE/EtOH) result from the acid hydrolysis of lignocellulosic biomass in ethanol. In this paper, derived cetane numbers are established for a wide variety of blend fractions, using Ignition Quality Tester measurements. EL/DEE/EtOH mixtures of ignition quality equivalent to market diesel and gasoline are identified. One mixture of Motor Octane Number (MON) 88.3 and Research Octane Number (RON) 95 is selected for detailed anal. in comparison to a FACE (Fuels for Advanced Combustion Engines) gasoline, as a representative of petroleum-derived gasoline, with a similar MON of 88.8 and RON of 94.4. Ignition delay times for the EL/DEE/EtOH gasoline fuel are measured using a rapid compression machine at equivalence ratios of 0.5 and 1.0, at 20 and 40 bar over a temperature range of 600-900 K. The data shows that at temperatures >800 K, the EL/DEE/EtOH fuel behaves quite similar to the petroleum derived gasoline, FACE-F. However, the tri-component biofuel shows a dramatically truncated extent of ignition reactivity at lower temperatures, with a total absence of low-temperature chem. or neg. temperature coefficient (NTC) region; in this respect this biofuel blend is very different to conventional gasoline. To understand this differing behavior, a detailed chem. kinetic model is developed. Anal. of this model shows that ignition of the EL/DEE/EtOH blend is inhibited by the dominance of alkyl radical elimination pathways, which leads to a heightened rate of production of HO2 radicals. At high temperatures, while both fuels maintain a similar ignition delay time, the sensitivity anal. and the radical pool population shows that a different combustion mechanism is occurring for the EL/DEE/EtOH fuel, where Et and Me radicals play a much more prominent role in the ignition process.
Sustainable Energy & Fuels published new progress about Acid hydrolysis. 539-88-8 belongs to class esters-buliding-blocks, name is Ethyl 4-oxopentanoate, and the molecular formula is C7H12O3, Related Products of esters-buliding-blocks.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics