Fernandez-Mateos, A. published the artcileRadical Cyclization of Epoxy Vinyl- and Allylsulfones Promoted by Titanocene Chloride, Name: Ethyl 5-methylhex-5-enoate, the main research area is radical cyclization epoxy vinyl allylsulfone titanocene.
A titanocene-mediated intramol. radical addition of different epoxy vinyl- and allylsulfones has been achieved. Five- and six-membered ring products were obtained in good to excellent yields in the presence of both 2.2 and 0.2 equiv of Cp2TiCl. A novel double-activation strategy allowed us to achieve small-size rings such as cyclobutanes and cyclopropanes.
Journal of Organic Chemistry published new progress about Radical cyclization. 39495-82-4 belongs to class esters-buliding-blocks, name is Ethyl 5-methylhex-5-enoate, and the molecular formula is C9H16O2, Name: Ethyl 5-methylhex-5-enoate.
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