Voutyritsa, Errika published the artcilePhotocatalytic atom transfer radical addition to olefins utilizing novel photocatalysts, Computed Properties of 583-04-0, the main research area is ruthenium photocatalyst atom transfer radical addition; ATRA reactions; olefins; photocatalysis; ruthenium-based complexes; sustainable catalysis.
Photocatalysis is a rapidly evolving area of research in modern organic synthesis. Among the traditional photocatalysts, metal-complexes based on ruthenium or iridium are the most common. Herein, we present the synthesis of two photoactive, ruthenium-based complexes bearing pyridine-quinoline or terpyridine ligands with extended aromatic conjugation. Our complexes were utilized in the atom transfer radical addition (ATRA) of haloalkanes to olefins, using bromoacetonitrile or bromotrichloromethane as the source of the alkyl group. The tailor-made ruthenium-based catalyst bearing the pyridine-quinoline bidentate ligand proved to be the best-performing photocatalyst, among a range of metal complexes and organocatalysts, efficiently catalyzing both reactions. These photocatalytic atom transfer protocols can be expanded into a broad scope of olefins. In both protocols, the photocatalytic reactions led to products in good to excellent isolated yields.
Molecules published new progress about Alkenes Role: BSU (Biological Study, Unclassified), BIOL (Biological Study). 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Computed Properties of 583-04-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics