Wang, Juan-Juan published the artcileAnti-Markovnikov Hydroazidation of Alkenes by Visible-Light Photoredox Catalysis, Name: Allyl benzoate, the main research area is alkene anti Markovnikov hydroazidation regioselective photocatalyst; hydroazidation; photoredox catalysis; radical reactions; trimethylsilyl azide; water.
The anti-Markovnikov hydroazidation of alkenes has been accomplished under visible-light irradiation by using [Ir(dF(CF3)ppy)2(dtbbpy)]PF6 as the photocatalyst and trimethylsilyl azide as the azidating agent. The reactions were greatly facilitated by water, the beneficial effect of which can be attributed to its participation in the reaction as the hydrogen donor, as indicated by deuterium isotope experiments The reactions proceed under solvent free conditions in the presence of water. 4-Dimethylaminopyridine also exhibited a beneficial effect on the reactions. The present method enabled hydroazidation of several types of unactivated alkenes with good yields and high regioselectivity.
Chemistry – A European Journal published new progress about Azidation (hydro). 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Name: Allyl benzoate.
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Ester – an overview | ScienceDirect Topics