Penrhyn-Lowe, Oliver B. published the artcileImpact of multi-vinyl taxogen dimensions on high molecular weight soluble polymer synthesis using transfer-dominated branching radical telomerisation, Application of Dodecyl 2-methylacrylate, the main research area is vinyl taxogen transfer dominated branching radical telomerisation.
Complex macromol. architectures offer innovation opportunities through the formation of new polymers with novel phys. and chem. behavior. Optimally existing com. feedstocks are used as the introduction of new small mol. chemistries may extend regulatory requirements at high expense. In a highly orthogonal synthesis strategy, we recently utilized telomerisation approaches, conventionally targeting small mol. dimerization, to generate high mol. weight branched polymers. Transfer-dominated branching radical telomerisation (TBRT) employs radical reactions, but yields branched polymers with extended backbones resembling those conventionally formed via step-growth polymerization Here we examine the impact of taxogen dimensions on the outcomes of TBRT using multi-vinyl taxogens ethylene glycol dimethacrylate (EGDMA), 1,6-hexanediol dimethacrylate (HDMA) and 1,12-dodecanediol dimethacrylate (LDMA). Marked differences in gelation behaviors were correlated to the dimensions of the taxogen, notably due to the shifting balance of intermol. and intramol. branching processes occurring during TBRT.
Polymer Chemistry published new progress about Gelation. 142-90-5 belongs to class esters-buliding-blocks, name is Dodecyl 2-methylacrylate, and the molecular formula is C16H30O2, Application of Dodecyl 2-methylacrylate.
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