Patias, Georgios published the artcileControlled synthesis of methacrylate and acrylate diblock copolymers via end-capping using CCTP and FRP, Related Products of esters-buliding-blocks, the main research area is methacrylate acrylate diblock copolymer catalytic chain transfer polymerization.
Scalable methods of producing functional materials is of importance. Herein, we report the use of free radical copolymerization of ω-unsaturated methacrylic macromonomers, as derived from catalytic chain transfer polymerization (CCTP), with acrylic monomers in solution leading to block copolymers by varying the nature of the macromonomer. We demonstrate the effect that varying the mol. weight and ester side chain length of macromonomer from CCTP, has on the polymerization leading to either graft or diblock copolymers. DOSY NMR, MALDI-ToF/ToF MS has allowed for the exploration of the extent to which varying the concentration of macromonomer has on the products formed. Importantly, during the successful synthesis of acrylic and methacrylic diblock copolymers with broad dispersities of each block, full consumption of the macromonomers was observed
Polymer Chemistry published new progress about Polymers, graft Role: PRP (Properties), SPN (Synthetic Preparation), PREP (Preparation). 142-90-5 belongs to class esters-buliding-blocks, name is Dodecyl 2-methylacrylate, and the molecular formula is C16H30O2, Related Products of esters-buliding-blocks.
Referemce:
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