McCourt, Ruairi O. published the artcileAtmospheric Oxygen Mediated Radical Hydrothiolation of Alkenes, Computed Properties of 583-04-0, the main research area is alkene thiol atm oxygen mediated radical hydrothiolation; green chemistry; hydrothiolation; initiation; radical; thiol-ene.
A mild, metal-free, atm. oxygen-mediated radical hydrothiolation of alkenes (and alkyne) was reported. A variety of sulfur containing motifs including alkanethiols, thiophenols and thioacids undergo an atm. oxygen-mediated radical hydrothiolation reaction with a plethora of alkenes in good yield with excellent functional group compatibility, typically with short reaction times to furnished a range of functionalized products. Biomols. proved tolerant to the conditions and the procedure was robust and easily executable requiring no specialized equipment. Concise mechanistic studies confirmed that the process proceeded through radical intermediates in a thiol-ene reaction manifold. The methodol. offered an efficient “”green”” approach for thiol-ene mediated “”click”” ligation and a milder alternative to thermally initiated hydrothiolation processes.
Chemistry – A European Journal published new progress about Green chemistry. 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Computed Properties of 583-04-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics