Oxidation of alcohols to carbonyl compounds via alkoxysulfonium ylides: the Moffat, Swern, and related oxidations was written by Tidwell, Thomas T.. And the article was included in Organic Reactions (Hoboken, NJ, United States) in 1990.Computed Properties of C12H18O3 The following contents are mentioned in the article:
A review of the article Oxidation of alcs. to carbonyl compounds via alkoxysulfonium ylides: the Moffat, Swern, and related oxidations This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Computed Properties of C12H18O3).
(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Computed Properties of C12H18O3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics