Polymerization of fluorine-containing vinyl monomers, 1. Monomer reactivity ratios and Q, e-values of fluoroalkyl acrylates and methacrylates was written by Narita, Tadashi;Hagiwara, Tokio;Hamana, Hiroshi. And the article was included in Makromolekulare Chemie, Rapid Communications in 1985.Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate The following contents are mentioned in the article:
The e values in the polymerization of 2,2,2-trifluoromethyl or 2,2,2-trifluoro-1-(trifluoromethyl)ethyl (meth)acrylates with styrene [100-42-5] (calculated from reactivity ratios) and σ values (calculated using the relation between e and Hammett σ values) showed an electron-withdrawing inductive effect of fluoroalkyl ester groups. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate).
1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics