Highly regioselective and chemoselective titanocene mediated Barbier-type allylation reactions was written by Morcillo, Sara P.;Martinez-Peragon, Angela;Jakoby, Verena;Mota, Antonio J.;Kube, Christian;Justicia, Jose;Cuerva, Juan M.;Gansaeuer, Andreas. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2014.Recommanded Product: 37905-02-5 The following contents are mentioned in the article:
Titanocene carboxylate is an excellent chemoselective reagent for unprecedented α-regioselective Barbier-type reactions. It constitutes the first titanocene(III) able to tolerate epoxides and readily reduced carbonyl compounds, such as aromatic and α,β-unsaturated aldehydes. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Recommanded Product: 37905-02-5).
(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Recommanded Product: 37905-02-5
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics