Intramolecular Formal oxa-[3 + 3] Cycloaddition Approach to the ABD System of Phomactin A was written by Cole, Kevin P.;Hsung, Richard P.. And the article was included in Organic Letters in 2003.Related Products of 37905-02-5 The following contents are mentioned in the article:
The ABD-ring I of phomactin A was synthesized using an intramol. formal oxa-[3 + 3] cycloaddition of an α,β-unsaturated iminium salt tethered to a 1,3-diketone. This represents the first time that the 12-membered ring has been formed simultaneously with the 1-oxadecalin and should afford a facile route to the challenging structure of phomactin A. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Related Products of 37905-02-5).
(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Related Products of 37905-02-5
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics