Selective oxidation of benzyl ethers with ammonium chlorochromate in the dry state was written by Chen, Mi-Feng;Ding, Li;Cai, Kun;Liu, Liang-Xian;Liu, Feng. And the article was included in Youji Huaxue in 1995.Product Details of 5444-75-7 The following contents are mentioned in the article:
A new application of ammonium chlorochromate (I) as an efficient oxidant for benzyl ethers was reported. Without solvent, benzyl ethers are selectively oxidized by I to the corresponding benzoates in satisfactory yields. E.g., oxidation of PhCH2OMe with I at 70° for 21 h gave 72% BzOMe. This study involved multiple reactions and reactants, such as 2-Ethylhexyl benzoate (cas: 5444-75-7Product Details of 5444-75-7).
2-Ethylhexyl benzoate (cas: 5444-75-7) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Product Details of 5444-75-7
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics