Tuning Surface Properties of Poly(methyl methacrylate) Film Using Poly(perfluoromethyl methacrylate)s with Short Perfluorinated Side Chains was written by Sohn, Eun-Ho;Ha, Jong-Wook;Lee, Soo-Bok;Park, In Jun. And the article was included in Langmuir in 2016.Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate The following contents are mentioned in the article:
To control the surface properties of a commonly used polymer, poly(Me methacrylate) (PMMA), poly(perfluoromethyl methacrylate)s (PFMMAs) with short perfluorinated side groups (i.e., -CF3, -CF2CF3, -(CF3)2, -CF2CF2CF3) were used as blend components because of their good solubility in organic solvents, low surface energies, and high optical transmittance. The surface energies of the blend films of PFMMA with the -CF3 group and PMMA increased continuously with increasing PMMA contents from 17.58 to 25.97 mN/m, whereas those of the other polymer blend films remained at low levels (10.24-12.59 mN/m), similar to those of pure PFMMAs, even when the blends contained 90 weight% PMMA. Surface morphol. and composition measurements revealed that this result originated from the different blend structures, such as uniform distribution and vertical phase separation We expect that these PFMMAs will be useful in widening the applicable window of PMMA. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate).
1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics