Chen, Hongtai published the artcileRobust Heterometallic TbIII/MnII-Organic Framework for CO2/CH4 Separation and I2 Adsorption, Safety of Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)isophthalate, the publication is ACS Applied Nano Materials (2020), 3(3), 2680-2686, database is CAplus.
The exquisite combination of heterometallic [TbIIIMnII(CO2)3(H2O)2] clusters with the hexacarboxylate ligand of H6TDP generates one water-stable 3D heterometallic TbIII/MnII-organic framework material {[TbMn(HTDP)(H2O)2]·5DMF·4H2O}n (NUC–3; H6TDP = 2,4,6-tri(2′,4′-dicarboxyphenyl)pyridine), which consists of functionalized noninterspersed opening nanochannels shaped by six rows of [TbIIIMnII(CO2)3(H2O)2] clusters. Based on the single-component sorption measurements, activated NUC–3 framework exhibits effective CO2/CH4 separation associated with high uptake and moderate adsorption enthalpy of CO2. Dynamic breakthrough experiments reveal that NUC–3 could be competent for the separation of CO2/CH4 (50:50, v:v) mixture Moreover, the kinetic and equilibrium experiments of iodine adsorption indicate that NUC–3 possess excellent adsorption capacity for iodine mols. in cyclohexane solution The excellent structural stability and functional internal surface makes NUC–3 a prospective adsorbent for practical CO2/CH4 separation and adsorption elimination of iodine mols., opening up the insight of heterometallic MOFs for pratical application.
ACS Applied Nano Materials published new progress about 1186376-95-3. 1186376-95-3 belongs to esters-buliding-blocks, auxiliary class Boronic acid and ester, name is Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)isophthalate, and the molecular formula is C16H21BO6, Safety of Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)isophthalate.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics