Iron-catalysed 1,2-aryl migration of tertiary azides was written by Wei, Kaijie;Yang, Tonghao;Chen, Qing;Liang, Siyu;Yu, Wei. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2020.Related Products of 106-73-0 The following contents are mentioned in the article:
The 1,2-Aryl migration of α,α-diaryl tertiary azides RC(R1)(C6H5)N3 (R = Ph, 4-fluorophenyl, iso-Pr, iso-Bu, etc.; R1 = 4-methylphenyl, Et, phenyl) was achieved by using the catalytic system of FeCl2/N-heterocyclic carbene (NHC) SIPr.HCl. The reaction generated aniline products RCHR1NHC6H5 in good yields after one-pot reduction of the migration-resultant imines. This study involved multiple reactions and reactants, such as Methyl heptanoate (cas: 106-73-0Related Products of 106-73-0).
Methyl heptanoate (cas: 106-73-0) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Related Products of 106-73-0
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics