Allylic oxidation of olefins by catalytic and stoichiometric selenium dioxide with tert-butyl hydroperoxide was written by Umbreit, M. A.;Sharpless, K. B.. And the article was included in Journal of the American Chemical Society in 1977.Synthetic Route of C12H18O3 The following contents are mentioned in the article:
Reactive olefins were oxidized to the allylic alcs. and carbonyl compounds by catalytic SeO2 in the presence of excess Me3COOH (I). Olefins normally unreactive toward SeO2 were readily oxidized at room temperature to the unrearranged allylic products in good yields by stoichiometric SeO2 and I. I suppresses generation of Se(0) and Se(II) species, which ordinarily complicate the reaction of SeO2 with olefins. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Synthetic Route of C12H18O3).
(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Synthetic Route of C12H18O3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics