Anomeric Thioglycosides Give Different Anomeric Product Distributions under NIS/TfOH Activation was written by Trinderup, Helle H.;Sandgaard, Tatjana L. P.;Juul-Madsen, Line;Jensen, Henrik H.. And the article was included in Journal of Organic Chemistry in 2022.Recommanded Product: 604-69-3 The following contents are mentioned in the article:
The reaction of a series of anomeric thioglycosides with various glycosyl acceptors and N-iodosuccinimide/catalytic triflic acid was investigated with respect to reactivity and anomeric selectivity. In general, β-configured donors were found to give a more β-selective reaction outcome compared to their α-configured counterparts. The relative reactivity of various thioglycosides was measured through competition experiments, and the following order was established: Ph, tolyl, Me, Et, iso-Pr, and 1-adamantyl. This study involved multiple reactions and reactants, such as (2S,3R,4S,5R,6R)-6-(Acetoxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl tetraacetate (cas: 604-69-3Recommanded Product: 604-69-3).
(2S,3R,4S,5R,6R)-6-(Acetoxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl tetraacetate (cas: 604-69-3) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Recommanded Product: 604-69-3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics