Geraniol and nerol in organic synthesis. Useful intermediates for the synthesis of C17-juvenile hormone was written by Grieco, Paul A.. And the article was included in Journal of the Chemical Society, Chemical Communications in 1972.Application In Synthesis of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:
Ozonolysis of cis-AcOCH2CH:CMe(CH2)2CH:CMe2 (I) at -78° in CH2Cl2 followed by treatment with Me2S gave 60% AcOCH2CH:CMe(CH2)2CHO which with (PPh3)3RhCl in C6H6 or CH2Cl2 gave 70% cis-AcOCH2CH:CMPr (II). SeO2 oxidation of the trans isomer of I followed by NaBH4 reduction in 95% EtOH at 0° gave 40% trans-trans-AcOCH2CH:CMe(CH2)2CH:CMeCH2OH (III). II and III are intermediates for the synthesis of C17-juvenile hormone. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Application In Synthesis of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).
(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Application In Synthesis of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics