Bakers’ yeast hydrogenation of carbonyl activated double bonds. Enantioselective synthesis of the (S)-form of the dihydroterpenediol secreted by Danaus chrysippus and of a pheromone of Callosobruchus chinensis L was written by Gramatica, Paola;Giardina, Giuseppe;Speranza, Giovanna;Manitto, Paolo. And the article was included in Chemistry Letters in 1985.Synthetic Route of C12H18O3 The following contents are mentioned in the article:
The (S)-form of (E)-3,7-dimethyl-2-octene-1,8-diol (I) (secreted by male danaid butterflies) and of (E)-3,7-dimethyl-2-octene-1,8-dioic acid (II) (a pheromone of the azuki bean weevil) were synthesized via stereoselective hydrogenation by baker’s yeast of the carbonyl activated double bond of achiral precursors III and IV. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Synthetic Route of C12H18O3).
(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Synthetic Route of C12H18O3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics