Fluorinated hybrid polymers by copolymerization of trialkylsilyl methacrylate with fluoroalkyl methacrylate was written by Fujiwara, Hirotada;Narita, Tadashi;Hamana, Hiroshi;Shimizu, Koichi. And the article was included in Polymer Journal (Tokyo, Japan) in 2002.Application In Synthesis of 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate The following contents are mentioned in the article:
Fluorinated hybrid polymers bearing alkylsilyl groups were synthesized by copolymerization of tributylsilyl methacrylate (NBSM) with 2,2,2-trifluoroethyl or 1-trifluoromethyl-2,2,2-trifluoroethyl methacrylate (TFEM or HxFIM). To estimate the sequential distribution of monomer units in copolymers, monomer reactivity of NBSM with TFEM or HxFIM under radical (Bu peroxide as initiator) and anionic (LiZnBuEt2 as initiator) polymerization conditions was studied by 1H NMR. Surface characteristics of hybrid polymers were examined by contact angle measurements. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Application In Synthesis of 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate).
1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Application In Synthesis of 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate
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