Electrochemical deacetylation of 1,3-dicarbonyl compounds was written by Fujimoto, Kazuo;Maekawa, Hirofumi;Matsubara, Yoshiharu;Nishiguchi, Ikuzo. And the article was included in Chemistry Letters in 1996.Computed Properties of C9H16O4 The following contents are mentioned in the article:
Mild deacetylation of 1,3-dicarbonyl compounds was achieved by halonium-ion mediated electrolysis. In this reaction, the supporting electrolyte including sodium halide NaX (X = Cl or Br) was essential since the reaction proceeded through substitution by a halonium ion, generated electrochem. at the anode, on active methine carbons followed by base-catalyzed deacetylation, and was terminated by reductive dehalogenation of the formed α-halo carbonyl compounds at the cathode. This study involved multiple reactions and reactants, such as Ethyl methyl adipate (cas: 18891-13-9Computed Properties of C9H16O4).
Ethyl methyl adipate (cas: 18891-13-9) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Computed Properties of C9H16O4
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics