Taib, Layla Ahmed’s team published research in Reaction Kinetics, Mechanisms and Catalysis in 133 | CAS: 517-23-7

Reaction Kinetics, Mechanisms and Catalysis published new progress about 517-23-7. 517-23-7 belongs to esters-buliding-blocks, auxiliary class Tetrahydrofuran,Ketone,Ester, name is 3-Acetyldihydrofuran-2(3H)-one, and the molecular formula is C26H41N5O7S, Safety of 3-Acetyldihydrofuran-2(3H)-one.

Taib, Layla Ahmed published the artcileSolvent-free synthesis of 4-substituted coumarins catalyzed by novel Bronsted acidic ionic liquids with perchlorate anion: a convenient and practical complementary method for pechmann condensation, Safety of 3-Acetyldihydrofuran-2(3H)-one, the publication is Reaction Kinetics, Mechanisms and Catalysis (2021), 133(1), 383-403, database is CAplus.

Herein, three novel sulfonic-functionalized Bronsted acidic ionic liquids containing perchlorate anion counterparts e.g., I were prepared These ionic liquid catalysts e.g., I were prepared through simple and ecofriendly procedures and then applied as efficient catalysts with high yields under solvent-free conditions for the synthesis of 4-substituted coumarins e.g., II through the Pechmann condensation of different phenols e.g., naphthalen-1-ol and β-ketoesters R(O)CH(R1)C(O)OR2 [R = Me, Ph; R1 = H; R2 = Et; R1R2 = -(CH2)2-]. Compared to previous works, the proposed method offers several benefits, such as cleaner reactions, decreased reaction times, high yields, and the lack of laborious workup or purification procedures. Particularly, these catalysts make the condensation of less activated phenols feasible. Besides the described benefits, this advanced protocol was applied successfully for the synthesis of coumarins e.g., III from γ-lactone as 3-acetyldihydrofuran-2(3H)-one. The simplicity in operation, applicability and feasibility of this protocol for diverse substrates make it an efficient alternative to conventional methods.

Reaction Kinetics, Mechanisms and Catalysis published new progress about 517-23-7. 517-23-7 belongs to esters-buliding-blocks, auxiliary class Tetrahydrofuran,Ketone,Ester, name is 3-Acetyldihydrofuran-2(3H)-one, and the molecular formula is C26H41N5O7S, Safety of 3-Acetyldihydrofuran-2(3H)-one.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics