Synthesis and properties of novel random copolymers made from N-acryloyl piperazine-based monomers and fluoroalkylmethacrylates was written by Shundrina, Inna K.;Bukhtoyarova, Aleksandra D.;Russkikh, Vladimlen V.;Parkhomenko, Dmitry A.;Shelkovnikov, Vladimir V.. And the article was included in Polymer Bulletin (Heidelberg, Germany) in 2015.Recommanded Product: 3063-94-3 The following contents are mentioned in the article:
New piperazine-based polymerizable monomers were synthesized to modify adhesive properties of fluoromethacrylic copolymer. The new monomers showed good ability to radical copolymerization with fluoroalkylmethacrylates. Amorphous glassy terpolymers were prepared with random distribution units in the macromols. and weight-average mol. weight (Mw) 110,000-130,000. The ratio of monomer units in the obtained copolymer is close to the ratio of the monomers in the starting mixture The terpolymers exhibited excellent solubility in THF, acetone and α,α,α-trifluorotoluene (TFT). The introduction of new monomers to the macromols. increased the glass-transition temperatures (Tg) of terpolymers, significantly improved their thermal stability and adhesion to the aluminum substrate. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Recommanded Product: 3063-94-3).
1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Recommanded Product: 3063-94-3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics