Facile functionalization of the isopropylidene terminus of acyclic monoterpenes by way of benzenesulfenyl chloride addition was written by Masaki, Yukio;Hashimoto, Kinji;Kaji, Kenji. And the article was included in Tetrahedron in 1984.Related Products of 37905-02-5 The following contents are mentioned in the article:
Addition reaction of RCH2CH:CMe2 [R = H, PhCH2O, CH2:CHCMe(OAc)CH2, 2,2-(methylenedioxy)propyl, etc.] with PhSCl gave the corresponding isomeric products RCH2CH(SPh)CMe2Cl and RCH2CHClCMe2SPh. Hydrolysis in the presence of silica gel, dehydrochlorination under neutral or weakly basic conditions, or dehydrochlorination under strongly basic conditions gave the hydroxy sulfides RCH2CH(SPh)CMe2OH, methallylic sulfides RCH2CH(SPh)CMe:CH2 (I), or vinyl sulfides RCH2C(SPh):CMe2, resp. I were converted to terminal trans-allylic alcs. RCH2CH:CMeCH2OH. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Related Products of 37905-02-5).
(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Related Products of 37905-02-5
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics